Diiron oxo reactivity in a weak-field environment

2-Phenoxypyridyl Dinucleating Ligands for Assembly of Diiron(II) Complexes: Efficient Reactivity with O[subscript 2] to Form (-Oxo)diiron(III) Units

A series of 2-phenoxypyridyl and 2-phenoxyimino ligands, H2L (2,2’-(5,5’-(1,2phenylenebis(ethyne-2,1-diyl))bis(pyridine-5,2-diyl))diphenol, where R = H, Me, or t-Bu, and R’ = H, or Ph) and H2BIPS ((3,3’-(1E,1’E)-(3,3’-sulfonylbis(3,1-phenylene)bis(azan-1-yl-1ylidene))bis(methan-1-yl-1-ylidene)bis(5-methylbiphenyl-2-ol)) were synthesized as platforms for non-heme diiron(II) protein model complex...

Studying chemical reactivity in a virtual environment.

Chemical reactivity of a set of reactants is determined by its potential (electronic) energy (hyper)surface. The high dimensionality of this surface renders it difficult to efficiently explore reactivity in a large reactive system. Exhaustive sampling techniques and search algorithms are not straightforward to employ as it is not clear which explored path will eventually produce the minimum ene...

predicting intention to adopt interorganizational linkages: a study in iranian automative indusrty supply chain in b2b environment

در این پایان نامه مسایل مربوط به ارتباطاط سازمانی و نحوه تاثیر گذاری فناوری اطلاعات بر روی آنها بررسی میشود. انواع مدلهای سازمانی و بررسی متغیرهای مختلف بصورت آماری از اهداف این پایان نامه می باشد. ارتباطاط edi در محیط های b2b هدف اصلی مدل های بررسی شده می باشد.

Evaluating the identity and diiron core transformations of a (μ-oxo)diiron(III) complex supported by electron-rich tris(pyridyl-2-methyl)amine ligands.

The composition of a (μ-oxo)diiron(III) complex coordinated by tris[(3,5-dimethyl-4-methoxy)pyridyl-2-methyl]amine (R(3)TPA) ligands was investigated. Characterization using a variety of spectroscopic methods and X-ray crystallography indicated that the reaction of iron(III) perchlorate, sodium hydroxide, and R(3)TPA affords [Fe(2)(μ-O)(μ-OH)(R(3)TPA)(2)](ClO(4))(3) (2) rather than the previous...

Weak Derived Environment Effect